Please use this identifier to cite or link to this item: https://idr.l3.nitk.ac.in/jspui/handle/123456789/11279
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dc.contributor.authorJanakiraman, S.
dc.contributor.authorSurendran, A.
dc.contributor.authorBiswal, R.
dc.contributor.authorGhosh, S.
dc.contributor.authorAnandhan, S.
dc.contributor.authorVenimadhav, A.
dc.date.accessioned2020-03-31T08:31:02Z-
dc.date.available2020-03-31T08:31:02Z-
dc.date.issued2019
dc.identifier.citationMaterials Research Express, 2019, Vol.6, 8, pp.-en_US
dc.identifier.urihttp://idr.nitk.ac.in/jspui/handle/123456789/11279-
dc.description.abstractElectrospinning is an efficient technique to produce ultrafine electroactive mat, diameters ranging from few nanometers to micrometers to use as a separator in sodium ion battery. The polyvinylidene fluoride (PVDF) polymer solution was optimized to 19 wt%, applied voltage 25 kV and flow rate of 0.5 ml h-1 to get a bead free ultrafine electroactive structure. The electroactive ?-phase is confirmed by x-ray diffractometer (XRD). Ionic conductivities, electrolyte uptake, wettability, linear sweep voltammetry (LSV) and thermal stability of the electroactive fibrous polymer electrolyte (EFPE) were studied by soaking the separator with a liquid electrolyte of 1 M sodium hexafluorophosphate (NaPF6) dissolved in ethylene carbonate (EC)/propylene carbonate (PC) (1:1 vol%). The EFPE exhibits high ionic conductivity of 1.08 mS cm-1 and electrochemical stability window of 5.0 V versus Na/Na+ under ambient condition. The half-cell containing Na0.66Fe0.5Mn0.5O2 as cathode and EFPE as the separator cum electrolyte showed a stable cycling performance at a current rate of 0.1C. 2019 IOP Publishing Ltd.en_US
dc.titleElectrospun electroactive polyvinylidene fluoride-based fibrous polymer electrolyte for sodium ion batteriesen_US
dc.typeArticleen_US
Appears in Collections:1. Journal Articles

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