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dc.contributor.authorOnkarappa, S.B.-
dc.contributor.authorDutta, Saikat-
dc.date.accessioned2020-03-31T08:36:00Z-
dc.date.available2020-03-31T08:36:00Z-
dc.date.issued2019-
dc.identifier.citationChemistrySelect, 2019, Vol.4, 19, pp.5540-5543en_US
dc.identifier.urihttps://idr.nitk.ac.in/jspui/handle/123456789/11966-
dc.description.abstractA series of 5-(alkoxymethyl)furfurals (AMFs) have been synthesized in excellent isolated yields (>90%) by reacting biomass-derived 5-(chloromethyl)furfural (CMF) or 5-(bromomethyl)furfural (BMF) with monohydric alkyl alcohols (methanol to 1-butanol) at slightly elevated temperatures (RT-50 C) and short reaction time (3 h). The modified work-up procedure minimizes side reactions while simplifying the isolation and purification of AMFs. Although higher primary alcohols like 1-pentanol and 1-hexanol and secondary alcohol like 2-propanol were found to be less reactive, use of N,N-diisopropylethylamine (DIPEA) as a base additive afforded AMFs in excellent yields within 6 h at 65 C using only slight excess of the alcohol (1.2 eq.) reagent. 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.titleHigh-Yielding Synthesis of 5-(alkoxymethyl)furfurals from Biomass-Derived 5-(halomethyl)furfural (X=Cl, Br)en_US
dc.typeArticleen_US
Appears in Collections:1. Journal Articles

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