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DC Field | Value | Language |
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dc.contributor.author | Friščić T. | - |
dc.contributor.author | Elacqua E. | - |
dc.contributor.author | Dutta, Saikat | - |
dc.contributor.author | Oburn S.M. | - |
dc.contributor.author | MacGillivray L.R. | - |
dc.date.accessioned | 2021-05-05T10:28:27Z | - |
dc.date.available | 2021-05-05T10:28:27Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Crystal Growth and Design Vol. 20 , 4 , p. 2584 - 2589 | en_US |
dc.identifier.uri | https://doi.org/10.1021/acs.cgd.9b01712 | - |
dc.identifier.uri | https://idr.nitk.ac.in/jspui/handle/123456789/15909 | - |
dc.description.abstract | A series of templated solid-state reactions are used to construct the â&tild;bent' isomer of the [2.2]cyclophane family of molecules. Small-molecule hydrogen-bond-donor templates based on resorcinol complete the supramolecular construction of ortho-, meta-, and para-[2.2]cyclophanes in the solid state. The family of exo,exo-dicyclobutyl[2.2]cyclophanes forms regiospecifically in up to quantitative yields. The confines of the organic solid state and the modular nature of the template approach allow for the generation of a less stable exo,endo-[2.2]metacyclophane by simply changing the template to enforce a concomitant change in self-assembly. Our results demonstrate the first completed solid-state construction of each member of the family of [2.2]cyclophanes. Copyright © 2020 American Chemical Society. | en_US |
dc.title | Total Syntheses Supramolecular Style: Solid-State Construction of [2.2]Cyclophanes with Modular Control of Stereochemistry | en_US |
dc.type | Article | en_US |
Appears in Collections: | 1. Journal Articles |
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