Please use this identifier to cite or link to this item: https://idr.l3.nitk.ac.in/jspui/handle/123456789/15909
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dc.contributor.authorFriščić T.-
dc.contributor.authorElacqua E.-
dc.contributor.authorDutta, Saikat-
dc.contributor.authorOburn S.M.-
dc.contributor.authorMacGillivray L.R.-
dc.date.accessioned2021-05-05T10:28:27Z-
dc.date.available2021-05-05T10:28:27Z-
dc.date.issued2020-
dc.identifier.citationCrystal Growth and Design Vol. 20 , 4 , p. 2584 - 2589en_US
dc.identifier.urihttps://doi.org/10.1021/acs.cgd.9b01712-
dc.identifier.urihttps://idr.nitk.ac.in/jspui/handle/123456789/15909-
dc.description.abstractA series of templated solid-state reactions are used to construct the â&tild;bent' isomer of the [2.2]cyclophane family of molecules. Small-molecule hydrogen-bond-donor templates based on resorcinol complete the supramolecular construction of ortho-, meta-, and para-[2.2]cyclophanes in the solid state. The family of exo,exo-dicyclobutyl[2.2]cyclophanes forms regiospecifically in up to quantitative yields. The confines of the organic solid state and the modular nature of the template approach allow for the generation of a less stable exo,endo-[2.2]metacyclophane by simply changing the template to enforce a concomitant change in self-assembly. Our results demonstrate the first completed solid-state construction of each member of the family of [2.2]cyclophanes. Copyright © 2020 American Chemical Society.en_US
dc.titleTotal Syntheses Supramolecular Style: Solid-State Construction of [2.2]Cyclophanes with Modular Control of Stereochemistryen_US
dc.typeArticleen_US
Appears in Collections:1. Journal Articles

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