Please use this identifier to cite or link to this item: https://idr.l3.nitk.ac.in/jspui/handle/123456789/9830
Full metadata record
DC FieldValueLanguage
dc.contributor.authorAnsari, R.M.-
dc.contributor.authorKumar, L.M.-
dc.contributor.authorBhat, B.R.-
dc.date.accessioned2020-03-31T06:51:32Z-
dc.date.available2020-03-31T06:51:32Z-
dc.date.issued2018-
dc.identifier.citationRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2018, Vol.44, 1, pp.-en_US
dc.identifier.uri10.1134/S1070328418010013-
dc.identifier.urihttp://idr.nitk.ac.in/jspui/handle/123456789/9830-
dc.description.abstractThe Co(II) complex [Co{C6H4 1,2-(N=CH C6H4O)2}] (I) and Ni(II) complex [Ni{C6H4 1,2-(N=CH C6H4O)2}] (II) with Schiff base of o-phenylenediamine and salicylaldehyde have been synthesized. The structure of the ligand and its complexes were derived on the basis of various techniques such as elemental analysis, mass, FT-IR, electronic spectra and magnetic susceptibility. From the Singal crystal X-ray diffraction (SCXRD) analysis techniques (CIF file CCDC no. 1498772 (II)), it has been confirmed that the Schiff base ligand (L), coordinates to the metal ion in a tetradentate fashion through the nitrogen and oxygen atom. In addition, the square planar geometry of Ni(II) complex also has been confirmed from SCXRD. Electronic spectra, mass spectra, and magnetic susceptibility measurements reveal square planar geometry for the Co(II) complex. Synthesized complexes were used in cross-coupling of arylhalides with phenylboronic acid. The transformation offers products in good yields using 0.02 mmol catalysts loading, thereby proving the efficiency of the complexes as catalysts for Suzuki Miyaura reaction. 2018, Pleiades Publishing, Ltd.en_US
dc.titleAir-Stable Cobalt(II) and Nickel(II) Complexes with Schiff Base Ligand for Catalyzing Suzuki Miyaura Cross-Coupling Reactionen_US
dc.typeArticleen_US
Appears in Collections:1. Journal Articles

Files in This Item:
File Description SizeFormat 
21 Air-Stable Cobalt(II).pdf591.84 kBAdobe PDFThumbnail
View/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.