Please use this identifier to cite or link to this item: https://idr.l3.nitk.ac.in/jspui/handle/123456789/13306
Title: Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands
Authors: Rudresha, B.J.
Ramachandra, Bhat, B.
Sampath, Kumar, H.C.
Shiva, Kumar, K.I.
Safakath, K.
Philip, R.
Issue Date: 2011
Citation: Synthetic Metals, 2011, Vol.161, 43987, pp.535-539
Abstract: This research article describes the synthesis, characterization and third-order nonlinear optical studies of copper(I) complexes [Cu(Br)(N,N?-C12H6N2O2) (PPh3)] and [Cu(I)(N,N?-C12H6N 2O2)(PPh3)] abbreviated as [CuBrLPPh 3] (1) and [CuILPPh3] (2) (L = 1,10-phenanthroline-5,6- dione). Nonlinear optical properties of the complexes are investigated at 532 nm using single beam Z-scan and degenerate four-wave mixing (DFWM) techniques employing nanosecond laser pulses. The complexes show optical limiting behaviour due to "effective" two-photon absorption. The values of the effective two-photon absorption (2PA) coefficients (?), third-order nonlinear susceptibilities (?(3)), and figures of merit (F), are calculated. 2010 Elsevier B.V. All rights reserved.
URI: http://idr.nitk.ac.in/jspui/handle/123456789/13306
Appears in Collections:1. Journal Articles

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